j chem soc jpn

J Jpn

y J . Am . Chem . Soc . 136 : 6453 − 6462

Cross-dehydrogenative coupling reactions between -ketoesters and electron-rich arenes, such as indoles, proceed with high regiochemical fidelity with a range of -ketoesters and indoles. The mechanism of the reaction between a prototypical ketoester, ethyl 2-oxocyclopentanonecarboxylate and N-methylindole, has been studied experimentally by monitoring the temporal course of the reaction by 1 ...

J Jpn

Hammond G S A correlation of reaction rates. J. Amer. Chem. Soc. 77:334-8, 1955

I began thinking about the subject of this paper while Iwas still in graduate school at Harvard and later during the year that I spent in postdoctoral work in Saul Winstein’s lab at UCLA. I realized that there were many series of related reactions in which there was a reasonable and intuitively attractive correlation between reaction rates and the strengths of bonds made or broken in the reacti...

Hammond G S A correlation of reaction rates. J. Amer. Chem. Soc. 77:334-8, 1955

I began thinking about the subject of this paper while Iwas still in graduate school at Harvard and later during the year that I spent in postdoctoral work in Saul Winstein’s lab at UCLA. I realized that there were many series of related reactions in which there was a reasonable and intuitively attractive correlation between reaction rates and the strengths of bonds made or broken in the reacti...